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1 article(s) from Lork, Enno

Clickable azide-functionalized bromoarylaldehydes – synthesis and photophysical characterization

Dominik Göbel,
Marius Friedrich,
Enno Lork and
Boris J. Nachtsheim

Beilstein J. Org. Chem. 2020, 16, 1683–1692, doi:10.3762/bjoc.16.139

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Graphical Abstract

Scheme 1: a) Schematic depiction of the Jablonski diagram. b) Schematic representation of El-Sayed’s rule.

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Figure 1: Top: literature examples of organic compounds showing RTP in the crystalline state (a) and in solut...

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Scheme 2: Reaction conditions for para-bromobenzaldehyde 3: a) 1) 2-amino-2-methylpropan-1-ol, 4 Å MS, CH₂Cl₂...

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Scheme 3: Reaction conditions: a) Br₂, Fe powder, CHCl₃, 0 °C, 4 h, 99%; b) KOH, KI, MeI, DMSO, 25 °C, 18 h, ...

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Scheme 4: Reaction conditions: a) 1) NaH, THF, 0 °C, 30 min; 2) MeI, THF, 0 °C to 25 °C, 2 h, 99%; b) 1) MeOT...

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Scheme 5: a) CuAAC reactions of azide-functionalized bromocarbaldehydes 3, 4 and 5 with terminal alkynes to t...

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Figure 2: a) Normalized UV–vis absorption spectra of 3 (blue line), 34 (olive line), 4 (green line) and 38 (r...

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Figure 3: a) Normalized UV–vis absorption spectra of 5 (blue line), 16 (green line), 42 (olive line) and 45 (...

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Published 14 Jul 2020

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